for many years. ^ The British Association for the Advancement of Science held a Sectional Dinner to which, according to tradition, only men were invited. Gertrude Robinson hosted “a dinner party at the same time as the Sectional Dinner, in the same hotel and with the same menu, to which she invited other women chemists as well as wives of the sectional officers and of other prominent members.†Following this event, all dinners of the British Association have been open to women. Plant Genetics Anthocyanins and Copigments Flowers, fruits, and leaves get their pigments from anthocyanins and copigments (such as tannings and flavonols). The combinations provide the exact colors of various plants at different stages of development. The Robinsons found that, at different ratios of anthocyanins to copigments, the copigments had different effects and they postulated that this was due to the copigments breaking up the anthocyanin complexes, which they observed when they were in solution together. They studied these pigments by comparing color distributions in immiscible solutions after reactions with alkalis or ferric chloride. Leucoanthocyanins The Robinsons investigated the structure of leucoanthocyanins, colorless molecules that generate anthocyanidins and are present in most plants. Rosenheim simultaneously discovered leucoanthocyanins and he coined the term. Leucoanthocyanins occur in more locations (wood, bark, nutshells, flowers, fruits) than normal anthocyanins. ^ The Robinsons, who lacked a machine with which to extract pigments, instead would cover the relevant plants with boards and then drive back and forth over them. Piloty-Robinson Pyrrole Synthesis This reaction, originally named after Piloty, had the Robinson name added to it due to their work on the mechanism. While it is unclear which Robinson the synthesis is technically named after, the paper on the topic was authored by both Gertrude and Robert. Generalized Synthesis This reaction is used to convert azines to 3,4-disubstituted pyrroles. Generalized Mechanism The mechanism as suggested by the Robinsons. There are, however, a few problems with some syntheses. The Piloty-Robinson reaction competes with the formation of pyrazoline when the reactant is an aliphatic azine derived from a ketone. Also, under high temperatures and highly acidic solutions, azines derived from aldehydes are not stable. This prevents the formation of 2,5-disubstituted pyrroles (where R=H) using this method. Modern Uses While the pyrroles produced by the Piloty-Robinson Synthesis are often very useful, the reaction itself is not always favorable because it requires high temperatures and long reaction times in addition to the problems mentioned above, the yield is often low or moderate. Modern methods have alleviated some of these concerns. Microwave Irradiation Microwave radiation decreases the time necessary for the reaction from around 3 days to 30-60 min. It can also affect the yield. Solid-Supported Solid-supported
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Agnes of Bavaria, Margravine of Brandenburg-Stendal Feet Size, Family, Eye Color, fees per movie, Wiki, body stats, Real Name, Profession
Agnes of Bavaria, Margravine of Brandenburg-Stendal Feet Size, Family, Eye Color, fees per movie, Wiki, body stats, Real Name, Profession
Agnes of Bavaria, Margravine of Brandenburg-Stendal Feet Size, Family, Eye Color, fees per movie, Wiki, body stats, Real Name, Profession
Agnes of Bavaria, Margravine of Brandenburg-Stendal Feet Size, Family, Eye Color, fees per movie, Wiki, body stats, Real Name, Profession
Agnes of Bavaria, Margravine of Brandenburg-Stendal Feet Size, Family, Eye Color, fees per movie, Wiki, body stats, Real Name, Profession
Agnes of Bavaria, Margravine of Brandenburg-Stendal Feet Size, Family, Eye Color, fees per movie, Wiki, body stats, Real Name, Profession
Agnes of Bavaria, Margravine of Brandenburg-Stendal Feet Size, Family, Eye Color, fees per movie, Wiki, body stats, Real Name, Profession.
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